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Nuclear History at the National Security Archive
This site has information on (and copies of many) declassified documents covering a broad range of topics. The most extensive materials are on the Cuban Missile Crisis. There is also a collection of documents on Predelegation of Authority for Nuclear Weapons Use , one on Multiple Independently Targetable Reentry Vehicles (MIRVs), and two "electronic briefing books" - one on China and the bomb, the other on monitoring nuclear tests in other countries ( The U.S Atomic Energy Detection System (AEDS) ).
http://www.gwu.edu/~nsarchiv/nsa/NC/nuchis.html
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